Application of radiation focusators for creation of nanoporous metal materials with high specific surface area by laser action

S.P. Murzin, V.I. Tregub, A.A. Melnikov, N.V. Tregub

PDF, 2902 kB

Full text of article: Russian language.

DOI: 10.18287/0134-2452-2013-37-2-226-232

Pages: 226-232.

Abstract:
Nanoporous metal material with high specific surface area was created under the action of laser radiation with the use of radiation focusators. The regimes of laser action under which nanoporous layer is formed in the centre of the thermal-affected zone on the surface of the material being investigated containing the products of reaction of cuprum and zinc in the alloy with the oxidizing medium. After laser treatment samples of brass L62 were exposed to plastic deformation and high temperature impact for the estimation of mechanical strength and heat resistance of the produced nanoporous material. Main part of the surface does not have destructions after the plastic deformation in two different modes and two high-temperature annealings, exfoliation of the porous layer was not observed, that is the evidence of sufficiently high mechanical strength and high resistance of the derived nanoporous material.

Key words:
laser action, metal material, nanoporous layer, surface.

References:

  1. Zhang, J. Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems / J. Zhang, C.M. Li // Chemical Society Reviews. – 2012. – Vol. 41, N 21. – P. 7016-7031.
  2. Nanostructured materials: processing, properties and applications / edition 2 by C.C. Koch. – Elsevier Science, 2007. – 784 p.
  3. Jin, H.-J. Bulk nanoporous metal for actuation / H.-J. Jin, J. Weissmüller // Advanced engineering materials. – 2010. – Vol. 12, N 8. – P. 714-723..
  4. Zabukovec Logar, N. Nanoporous materials: from catalysis and hydrogen storage to wastewater treatment / N. Zabukovec Logar, V. Kaucic // Acta chimica slovenica. – 2006. – Vol. 53. – P. 117-135.
  5. Ding, Y. Metallic mesoporous nanocomposites for electrocatalysis / Y. Ding, M. Chen, J. Erlebacher // Journal of the American Chemical Society. – 2004. – Vol. 126, N 22. – P. 6876-6877.
  6. Sun, L. Fabrication of nanoporous nickel by electrochemical dealloying / L. Sun, C.-L. Chien, P.C. Searson // Chemistry of materials. – 2004. – Vol. 16, N 16. – P. 3125-3129.
  7. Senior, N.A. Synthesis of tough nanoporous metals by controlled electrolytic dealloying / N.A. Senior, R.C. Newman // Nanotechnology. – 2006. – Vol. 17, N 9. – P. 2311-2316.
  8. Huang, T. The mechanism of three-dimensional manganese-based nanoporous structure formation by laser deposition coupled with dealloying / T. Huang, C. Dong, Y. Gu, M. Zhong, L. Li // Materials Letters. – 2013. – Vol. 95. – P. 30-32.
  9. Kazanskiy, N.L. Synthesis of nanoporous structures in metallic materials under laser action / N.L. Kazanskiy, S.P. Mur­zin, Ye.L. Osetrov, V.I. Tregub // Optics and Lasers in Engineering. – 2011. – Vol. 49, N 11. – P. 1264-1267.
  10. Murzin, S.P. Creation of metal materials nanoporous structures under the action of laser radiation / S.P. Murzin, N.L. Kazanskiy // ALT Proceedings. – 2012. – Vol. 1. – DOI: 10.12684/alt.1.43. – ISSN 2296-312X.
  11. Murzin, S.P. Exposure to laser radiation for creation of metal materials nanoporous structures / S.P. Murzin // Optics & Laser Technology. – 2013. – Vol. 48. – P. 509-512.
  12. Murzin, S.P. The research of intensification’s expedients for nanoporous structures formation in metal materials by the selective laser sublimation of alloy’s components / S.P. Murzin // Computer Optics. – 2011. – Vol. 35, N 2. – P. 175-179. – (In Russian).
  13. Doskolovich, L.L. Focusators for laser-branding / L.L. Do­skolovich, N.L. Kazanskiy, S.I. Kharitonov, G.V. Usplenjev // Optics and Lasers in Engineering. – 1991. – Vol. 15, N 5. – P. 311-322.
  14. Doskolovich, L.L. Analysis of quasiperiodic and geometric optical solutions of the problem of focusing into an axial segment / L.L. Doskolovich, N.L. Kazanskiy, V.A. Soifer, A.Ye. Tzaregorodtzev // Optik – International Journal for Light and Electron Optics. – 1995. – Vol. 101, N 2. – P. 37-41.
  15. Doskolovich, L.L. A method of designing diffractive optical elements focusing into plane areas / L.L. Doskolovich, N.L. Kazansky, S.I. Kharitonov, V.A. Soifer // Journal of Modern Optics. – 1996. – Vol. 43, N 7. – P. 1423-1433.
  16. Pavelyev, V.S. Formation of diffractive microrelief on diamond film surface / V.S. Pavelyev, S.A. Borodin, N.L. Kazanskiy, G.F. Kostyuk, A.V. Volkov // Optics & Laser Technology. – 2007. – Vol. 39, N 6. – P. 1234-1238.
  17. Kazansky, N.L. A research complex for solving computer optics problems / N.L. Kazanskiy // Computer optics. – 2006. – N 29. – P. 58-77. – (In Russian).
  18. Volkov, A.V. A method for the diffractive microrelief forming using the layered photoresist growth / A.V. Volkov, N.L. Kazanskiy, O.Yu. Moiseev, V.A. Soifer // Optics and Lasers in Engineering. – 1998. – Vol. 29, N 4-5. – P. 281-288.
  19. Bezus, E.A. Evanescent-wave interferometric nanoscale photolithography using guided-mode resonant gratings / E.A. Bezus, L.L. Doskolovich, N.L. Kazanskiy // Microelectronic Engineering. – 2011. – Vol. 88, N 2. – P. 170-174.
  20. Kazanskiy, N.L. Research & education center of diffractive optics / N.L. Kazanskiy // Proceedings of SPIE. – 2012. – Vol. 8410. – Art. No. 84100R.
  21. Murzin, S.P. Nanoporous structure formation in metal materials by cyclic elastoplastic deformation with laser action / S.P. Murzin, V.I. Tregub, E.L. Osetrov, A.M. Nikiforov // Proceedings of Samara RAS Scientific Centre. – 2010. – Vol. 12, N 4. – P. 182-185. – (In Russian).
  22. Murzin, S.P. Research of nanoporous structure formation mechanisms in multicomponent brass at a thermocycling by laser influence / S.P. Murzin // Proceedings of Samara RAS Scientific Centre. – 2012. – Vol. 14, N 4-1. – P. 270-274. – (In Russian).
  23. Murzin, S.P. Thermocycling with pulse-periodic laser action for formation of nanoporous structure in metal material / S.P. Murzin, V.I. Tregub, E.V. Shokova, N.V. Tregub // Computer Optics. – 2013. – Vol. 37, N 1. – P. 99-104. – ISSN 0134-2452. – (In Russian).
  24. Koh, K.A. Porous coordination copolymer with over 5000 m2/g BET surface area / K.A. Koh, A.G. Wong-Foy, A.J. Matzger // Journal of the American chemical society. – 2009. – Vol. 131, N 12. – P. 4184-4185.
  25. LIA handbook of laser materials processing / edited by J.F. Ready. – Orlando: Laser institute of America. Magnolia publishing, Inc., 2001. – 715 р.

© 2009, IPSI RAS
Institution of Russian Academy of Sciences, Image Processing Systems Institute of RAS, Russia, 443001, Samara, Molodogvardeyskaya Street 151; e-mail: ko@smr.ru; Phones: +7 (846 2) 332-56-22, Fax: +7 (846 2) 332-56-20