A method to improve the resolution of the diffraction spectrophotometer
D.S. Mikhailova
Siberian State University of Geosystems and Technology, Novosibirsk, Russia
Full text of article: Russian language.
PDF
Abstract:
In a number of situations, the resolution of modern spectrometers may be not high enough. This communication describes the use of an auxiliary interferometer together with a diffraction spectrometer, thus enabling its resolution and sensitivity to be enhanced during spectroscopy of adsorbed molecular layers. In this way, the industrial device is turned into a combined diffraction-interference monochromator. Numerical calculations and experiments show that the resolution of the combined diffraction spectrometer can be enhanced by an order of magnitude. In addition, the described device is a tunable multi-beam interferometer, allowing scanning through the spectrum. Scanning is done by turning the multi-beam interferometer. The article provides experimental data on adjusting the interferometer by tilting it with respect to incident radiation. Provision is made for the adjustment of the device by using a piezo plate. The increased sensitivity of the combined device allows it to be used as a spectrum analyzer of adsorbed substances. The design of the attachment provides an easy-to-install fitting for the input of the substance under test.
Keywords:
resolving power, free spectral region, multibeam interference.
Citation:
Mikhailova DS. A method to improve the resolution of the diffraction spectrophotometer. Computer Optics 2016; 40(6): 850-854. DOI: 10.18287/2412-6179-2016-40-6-850-854.
References:
- Waasem N, Buse K, Kühnemann F. High-sensivity photoacoustic absorption spectroscopy of non-linear optical materials. Proc SPIE 2013; 8621: 862109. DOI: 10.1117/12.2005871.
- Domaradzki J, Kaczmarek D, Wojcieszak D, Mazur M. Investigations of reversible optical transmission in gasochromic (Ti-V-Ta)Ox thin film for gas sensing applications. Sensors and Actuators B 2014; 201: 420-425. DOI: 10.1016/j.snb.2014.04.084.
- Kotlikov EN, Novikova YuA. Investigation of the optical films BAχMg1-χF2. Optics and Spectroscopy 2014; 117(3): 396-400.
- Morozov AN, Kochikov IV, Novgorod AV, Sologub AA, Fufurin IL. A statistical evaluation of the probability of correct detection of substances in Fourier transform infrared spectrometry [In Russian]. Computer Optics 2015; 39(4): 614-621. DOI: 10.18287/0134-2452-2015-39-4-614-621.
- Kiselev AV, Lygin VI. Infrared spectra of surface compounds adsorbed substance [In Russian]. Moscow: “Nauka” Publisher; 1972.
- Polunin KE, Dzardanov DV, Sokolova NP, Gorbunov AM, Bulgakova RA, Polunina IA. Study of the composition of the adsorption layers on TiO2 stilbenes by the method of IR-spectroscopy [In Russian]. Sorption and chromatographic processes 2008; 8(5): 796-806.
- Akopyan ME. Molecular photoinduced processes on the gas–solid boundary [In Russian]. Soros Educational Journal 1998; 2: 115-120.
- Civiš S, Ferus M, Zukalová M, Kavan L, Zelinger Z. The application of high-resolution IR spectroscopy and isotope labeling for detailed investigation of TiO2/gas interface reactions. Optical Materials 2013; 36(1): 159-162.
- Lazneva EF. Lazernaia desorbtsiia [In Russian]. Leningrad: LGU Publishing house; 1990.
- Komolov AS, Lazneva EF, Turiyev AM. Laser-induced desorption of atomic and molecular fragments from a tin dioxide surface modified by a thin organic covering of copper phthalocyanine. Semiconductors 2012; 46(1): 45-48. DOI: 10.1134/S1063782612010125.
- Petrov YuN, ed., Kravchenko VA, Orlov AN, Prokhorov AM. Resonant heterogeneous processes in a laser field [In Russian]. Moscow: “Nauka” Publisher; 1988.
- Ezhevskaja T, Bublikov A. FTIR spectrometers with special prefixes (FTIR, IR microscope etc.). Measurement Features [In Russian]. Analytics 2012; 1(2): 38-45.
- Lebedeva VV. Experimental optics [In Russian]. Moscow: Moscow University Publisher; 2005.
- Chesnokov VV, Chesnokov DV, Syrneva AS, Mikhailova DS. Interference gas spectrum analyzers [In Russian]. Interexpo GeoSibir 2012; 1(5): 66-70.
- Chesnokov VV, Chesnokov DV, Syrneva AS, Mikhailova DS. Spectral characteristics of the combined spectral devices Fabry-Perot interferometer [In Russian]. Interexpo GeoSibir 2012; 1(5): 166-175.
- Harrison GR, Lord RC, Loofbourow JR. Practical spectroscopy. 2nd ed. London, Glasgow: Blackie & Son Ltd.; 1949.
- Gribov LA. Obtaining Concentration Histograms of Mixtures by Spectral Methods. J Appl Spectrosc 2014; 81(2): 288-292. DOI: 10.1007/s10812-014-9923-8.
- Sperling BA, Hoang J, Kimes WA, Maslar JE. Time-resolved surface infrared spectroscopy during atomic layer deposition. Appl Spectrosc 2013; 67(9): 1003-1012. DOI: 10.1366/13-06995.
- Born M, Wolf E. Principles of optics: electromagnetic theory of propagation, interference and diffraction of light. 4th ed. Oxford, New York: Pergamon Press; 1969. ISBN: 978-0-080-13987-6.
© 2009, IPSI RAS
Institution of Russian Academy of Sciences, Image Processing Systems Institute of RAS, Russia, 443001, Samara, Molodogvardeyskaya Street 151; E-mail: journal@computeroptics.ru; Phones: +7 (846) 332-56-22, Fax: +7 (846) 332-56-20