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An Improved Method for Palladium Nanoparticles Detection on Carbon Materials in Scanning Electron Microscope Images
M.Yu. Kurbakov1, V.V. Sulimova1, O.S. Seredin1, A.V. Kopylov1
1 Tula State University, 300012, Russia, Tula, Lenina Ave. 92
Full text (PDF)
DOI: 10.18287/COJ1825
Article ID: 1825
Language: English
Abstract:
The subject of this paper is the urgent problem of detecting palladium nanoparticles on car-bon materials in grayscale scanning electron microscope images, the solution of which can be useful in many technological processes of the chemical industry. This is nontrivial problem and, currently, there is no method that would have all the necessary qualities for its solution.
This work is based on our previously developed method for detecting nanoparticles based on exponential approximation, which showed the best accuracy for scanning electron microscope images in absence of essential background irregularities. However, it has two significant shortcomings: 1) high demands on computing resources and 2) in the presence of background irregularities it produces a large number of false positives. This paper proposes a method that preserves the basic assumptions and general concept and, accordingly, the main advantages of earlier proposed approach, however, it contains a number of significant improvements that allow eliminating the above-mentioned shortcomings.
Experiments show that the proposed method reduces the number of false positives by 60-70% for SEM images with background irregularities while decreasing the nanoparticle detection time by approximately two to three times compared with the previously proposed approach.
Keywords:
noisy image analysis, nanoparticle detection, exponential approximation with shift.
Acknowledgements:
This research is funded by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state task FEWG-2024-0001. The authors thank the Scientific School of Academic V.P. Ananikov for the research topic, useful discussions and provided experimental data.
Citation:
Kurbakov MY, Sulimova VV, Seredin OS, Kopylov AV. An Improved Method for Palladium Nanoparticles Detection on Carbon Materials in Scanning Electron Microscope Images. Computer Optics 2026; 50(3): 1825. doi: 10.18287/COJ1825.
References:
- Morishita K, Takarada T. Scanning electron microscope observation of the purification behaviour of carbon nanotubes. J Mater Sci 1999; 34(5): 1169-1174. doi:10.1023/A:1004544503055.
- Pentsak EO, Kashin AS, Polynski MV, Kvashnina KO, Glatzel P, Ananikov VP. Spatial imaging of carbon reactivity centers in Pd/C catalytic systems. Chem Sci 2015; 6(6): 3302-3313. doi:10.1039/C4SC00232F.
- Boiko DA, Pentsak EO, Cherepanova VA, Gordeev EG, Ananikov VP. Deep neural network analysis of nanoparticle ordering to identify defects in layered carbon materials. Chem Sci 2021; 12(25): 7428-7441. doi:10.1039/D0SC05696K.
- Fei Z, Rodin AS, Gannett W, et al. Electronic and plasmonic phenomena at graphene grain boundaries. Nat Nanotechnol 2013; 8(11): 821-825. doi:10.1038/nnano.2013.197.
- Otsu N. A threshold selection method from gray-level histograms. IEEE Trans Syst Man Cybern 1979; 9(1): 62-66. doi:10.1109/TSMC.1979.4310076.
- Groom DJ, Yu K, Rasouli S, Polarinakis J, Bovik AC, Ferreira PJ. Automatic segmentation of inorganic nanoparticles in BF TEM micrographs. Ultramicroscopy 2018; 194: 25-34. doi:10.1016/j.ultramic.2018.06.002.
- Kaya E, Kaya O, Alkan G, Gürmen S, Stopic S, Friedrich B. New proposal for size and size-distribution evaluation of nanoparticles synthesized via ultrasonic spray pyrolysis using search algorithm based on image-processing technique. Materials 2020; 13(1): 38. doi:10.3390/ma13010038.
- Vippola M, Valkonen M, Sarlin E, Lepistö T. Insight to nanoparticle size analysis: novel and convenient image analysis method versus conventional techniques. Nanoscale Res Lett 2016; 11: 169. doi:10.1186/s11671-016-1391-z.
- Wu Y, Wang W, Zhang F, Xiao Z, Wu J, Geng L. Nanoparticle size measurement method based on improved watershed segmentation. In: Proc 2018 Int Conf Electronics and Electrical Engineering Technology (EEET 2018); 2018. pp. 232-237. doi:10.1145/3277453.3286087.
- Slater TJA, Wang YC, Leteba GM, Quiroz J, Camargo PHC, Haigh SJ, Allen CS. Automated single-particle reconstruction of heterogeneous inorganic nanoparticles. Microsc Microanal 2020; 26(6): 1168-1175. doi:10.1017/S1431927620024642.
- Boiko DA, Sulimova VV, Kurbakov MY, Kopylov AV, Seredin OS, Cherepanova VA, Pentsak EO, Ananikov VP. Automated recognition of nanoparticles in electron microscopy images of nanoscale palladium catalysts. Nanomaterials 2022; 12(21): 3914. doi:10.3390/nano12213914.
- Shvedchenko DO, Suvorova EI. Combination of thresholding and fitting methods for measuring nanoparticle sizes and size distributions in (S)TEM. Microsc Res Tech 2017; 80(10): 1113-1122. doi:10.1002/jemt.22908.
- Nesterenko DV. Formation and processing of electron microscopic images. Comput Opt 2011; 35(2): 166-174.
- Kimori Y. Morphological image processing for quantitative shape analysis of biomedical structures: effective contrast enhancement. J Synchrotron Radiat 2013; 20(6): 848-853. doi:10.1107/S0909049513020761.
- Mirzaei M, Rafsanjani HK. An automatic algorithm for determination of the nanoparticles from TEM images using circular Hough transform. Micron 2017; 96: 86-95. doi:10.1016/j.micron.2017.02.008.
- Kook S, Zhang R, Chan Q, Aizawa T, Kondo K, Kudo H, Sako T. Automated detection of primary particles from transmission electron microscope images of soot aggregates in diesel engine environments. SAE Int J Engines 2016; 9(1): 279-296. doi:10.4271/2015-01-1991.
- López Gutiérrez JD, Abundez Barrera IM, Torres Gómez N. Nanoparticle detection on SEM images using a neural network and semi-synthetic training data. Nanomaterials 2022; 12(11): 1818. doi:10.3390/nano12111818.
- Luan X, Zhou Y, Tan X, Wang X, Mei X, Han X. Particle image detection based on Mask R-CNN combined with edge segmentation. J Appl Opt 2023; 44(1): 93-103. doi:10.5768/JAO202344.0102005.
- Wang Z, Fan L, Lu Y, Mao J, Huang L, Zhou J. TESN: transformers enhanced segmentation network for accurate nanoparticle size measurement of TEM images. Powder Technol 2022; 407: 117673. doi:10.1016/j.powtec.2022.117673.
- Okunev AG, Mashukov MY, Nartova AV, Matveev AV. Nanoparticle recognition on scanning probe microscopy images using computer vision and deep learning. Nanomaterials 2020; 10(7): 1285. doi:10.3390/nano10071285.
- Kharin AY. Deep learning for scanning electron microscopy: synthetic data for the nanoparticles detection. Ultramicroscopy 2020; 219: 113125. doi:10.1016/j.ultramic.2020.113125.
- Genc A, Marlowe J, Finzel J, Christopher P. AI-enhanced nanoparticle analysis: integrating single-shot object detection and vision transformer for rapid and accurate characterization. Microsc Microanal 2024; 30(S1): 1595-1596. doi:10.1093/mam/ozae044.196.
- Thuan ND, Cuong HM, Nam NH, Huong NTL, Hong HS. Morphological analysis of Pd/C nanoparticles using SEM imaging and advanced deep learning. RSC Adv 2024; 14: 35172-35183. doi:10.1039/D4RA06113F.
- Marsh BP, Chada N, Sanganna Gari RR, Sigdel KP, Gaffney KJ, Provost CR, Gage DJ, Craig SL, Bianculli RH, Doughty RB, Ros R. The Hessian blob algorithm: precise particle detection in atomic force microscopy imagery. Sci Rep 2018; 8(1): 978. doi:10.1038/s41598-018-19379-x.
- Bright DS, Steel EB. Two-dimensional top hat filter for extracting spots and spheres from digital images. J Microsc 1987; 146(2): 191-190. doi:10.1111/j.1365-2818.1987.tb01340.x.
- Boiko DA, Pentsak EO, Cherepanova VA, Ananikov VP. Electron microscopy dataset for the recognition of nanoscale ordering effects and location of nanoparticles – Dataset 1 (ordered). Figshare 2020. doi:10.6084/m9.figshare.11783661.
- Pedregosa F, Varoquaux G, Gramfort A, et al. Scikit-learn: machine learning in Python. J Mach Learn Res 2011; 12: 2825-2830.
- Vincent L. Morphological grayscale reconstruction in image analysis: applications and efficient algorithms. IEEE Trans Image Process 1993; 2(2): 176-201. doi:10.1109/83.217222.
- Zheng J, Hryciw RD. Segmentation of contacting soil particles in images by modified watershed analysis. Comput Geotech 2016; 73: 142-152. doi:10.1016/j.compgeo.2015.11.025.
- Lindeberg T. Scale-space theory in computer vision. Dordrecht: Kluwer Academic Publishers; 1994. doi:10.1007/978-1-4757-6465-9.
- Marr D, Hildreth E. Theory of edge detection. Proc R Soc Lond B Biol Sci 1980; 207(1167): 187-217.
- Kashin AS, Boiko DA, Ananikov VP. Neural network analysis of electron microscopy video data reveals the temperature-driven microphase dynamics in the ions/water system. Small 2021; 17(12): 2007726. doi:10.1002/smll.202007726.
- Lunts AL, Brailovskii VL. Estimation of features obtained in statistical recognition procedures. Izv Akad Nauk SSSR Ser Tekh Kibern 1969; 3: 3-12.
- Kurbakov MY, Sulimova VV, Kopylov AV, Seredin OS, Boiko DA, Pentsak EO, Cherepanova VA, Ananikov VP. Determining the orderliness of carbon materials with nanoparticle imaging and explainable machine learning. Nanoscale 2024; 16(32): 13663-13676. doi:10.1039/D4NR00952E.
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